{"id":2874,"date":"2012-04-25T10:31:11","date_gmt":"2012-04-25T09:31:11","guid":{"rendered":"http:\/\/emilkirkegaard.dk\/en\/?p=2874"},"modified":"2012-04-25T10:31:11","modified_gmt":"2012-04-25T09:31:11","slug":"thoughts-re-a-very-short-introduction-to-the-elements-philip-ball","status":"publish","type":"post","link":"https:\/\/emilkirkegaard.dk\/en\/2012\/04\/thoughts-re-a-very-short-introduction-to-the-elements-philip-ball\/","title":{"rendered":"Thoughts re. A very short introduction to The Elements (Philip Ball)"},"content":{"rendered":"<p style=\"padding-left: 30px;\">What this really means is that the classical elements are familiar<br \/>\nrepresentatives of the different physical states that matter can<br \/>\nadopt. Earth represents not just soil or rock, but all solids. Water is<br \/>\nthe archetype of all liquids; air, of all gases and vapours. Fire is a<br \/>\nstrange one, for it is indeed a unique and striking phenomenon.<br \/>\nFire is actually a dancing plasma of molecules and molecular<br \/>\nfragments, excited into a glowing state by heat. It is not a substance<br \/>\nas such, but a variable combination of substances in a particular<br \/>\nand unusual state caused by a chemical reaction. In experiential<br \/>\nterms, fire is a perfect symbol of that other, intangible aspect of<br \/>\nreality: light.<\/p>\n<p style=\"padding-left: 30px;\">The ancients saw things this way too: that elements were types, not<br \/>\nto be too closely identified with particular substances. When Plato<br \/>\nspeaks of water the element, he does not mean the same thing as<br \/>\nthe water that flows in rivers. River water is a manifestation of<br \/>\nelementary water, but so is molten lead. Elementary water is &#8216;that<br \/>\nwhich flows&#8217;. Likewise, elementary earth is not just the stuff in the<br \/>\nground, but flesh, wood, metal.<\/p>\n<p>I was first recently made aware of this interpretation before. It really makes the theory much more plausible and makes it more believable that bright people believed this to be true.<\/p>\n<p>&#8211;<\/p>\n<p style=\"padding-left: 30px;\">Lavoisier&#8217;s belief reveals that he still held a somewhat traditional<br \/>\nview of elements. They were generally regarded as being rather like<br \/>\ncolours or spices, having intrinsic properties that remain evident in<br \/>\na mixture. But this is not so. A single element can exhibit very<br \/>\ndifferent characteristics depending on what it is combined with.<br \/>\nChlorine is a corrosive, poisonous gas; combined with sodium in<br \/>\ntable salt, it is completely harmless. Carbon, oxygen, and<br \/>\nnitrogen are the stuff of life, but carbon monoxide and cyanide<br \/>\n(a combination of carbon and nitrogen) are deadly. This was a hard<br \/>\nnotion for chemists to accept. Lavoisier himself came under attack<br \/>\nfor claiming that water was composed of oxygen and hydrogen: for<br \/>\nwater puts out fires (it is &#8216;the most powerful antiphlogistic we<br \/>\npossess&#8217;, according to one critic), whereas hydrogen is hideously<br \/>\nflammable.<\/p>\n<p>An early example of the fallacy of <a href=\"http:\/\/www.fallacyfiles.org\/division.html\">division<\/a>\/<a href=\"http:\/\/www.fallacyfiles.org\/composit.html\">composition<\/a>.<\/p>\n<p>&#8211;<\/p>\n<p style=\"padding-left: 30px;\">Thus there is nothing optimal or ideal about living on an oxygen-<br \/>\nrich planet; it is simply the way things turned out. Oxygen is, after<br \/>\nall, an extremely abundant element: the third most abundant in<br \/>\nthe universe, and the most abundant (47 per cent of the total) in<br \/>\nthe Earth&#8217;s crust. On the other hand, the living world (the<br \/>\nbiosphere) has contrived to maintain the proportion of oxygen in<br \/>\nthe atmosphere at more or less the perfect level for aerobic<br \/>\n(oxygen-breathing) organisms like us. If there was less than 17<br \/>\nper cent oxygen in the air, we would be asphyxiated. If there was<br \/>\nmore than 25 per cent, all organic matter would be highly<br \/>\nflammable: it would combust at the slightest provocation, and<br \/>\nwildfires would be uncontrollable. A concentration of 35 per cent<br \/>\noxygen would have been enough to destroy most life on Earth in<br \/>\nglobal fires in the past. (NASA switched to using normal air<br \/>\nrather than pure oxygen in their spacecrafts for this reason, after<br \/>\nthe tragic and fatal conflagration during the first Apollo tests in<br \/>\n1967.) So the current proportion of 21 per cent achieves a good<br \/>\ncompromise.<\/p>\n<p style=\"padding-left: 30px;\">This constancy of the oxygen concentration in air lends support to<br \/>\nthe hypothesis that the biological and geological systems of the<br \/>\nEarth conspire to adjust the atmosphere and environment so that<br \/>\nthey are well suited to sustain life &#8211; the so-called Gaia hypothesis.<br \/>\nOxygen levels have fluctuated since the air became oxygen rich, but<br \/>\nnot by much. In addition, today&#8217;s proportion of atmospheric oxygen<br \/>\nis large enough to support the formation of the ozone layer in the<br \/>\nstratosphere, which protects life from the worst of the sun&#8217;s harmful<br \/>\nultraviolet rays. Ozone is a UV-absorbing form of pure oxygen in<br \/>\nwhich the atoms are joined not in pairs, as in oxygen gas, but in<br \/>\ntriplets.<\/p>\n<p>This smells like the &#8216;backwards&#8217; thinking that fuels the <a href=\"http:\/\/en.wikipedia.org\/wiki\/Argument_from_design\">arguments from design<\/a>. The reason that the oxygen level is &#8216;just right&#8217; for organisms, is that.. they have evolved to fit the current (or recent ancestral) levels of oxygen in the air.<\/p>\n<p>Also, the claims sound rather fishy, and i cudn&#8217;t either confirm or disconfirm when i tried with Wikipedia and Google.<\/p>\n<p>&#8211;<\/p>\n<p style=\"padding-left: 30px;\">And the crowning irony is that gold is the most useless of metals,<br \/>\nprized like a fashion model for its ability to look beautiful and do<br \/>\nnothing. Unlike metals such as iron, copper, magnesium,<br \/>\nmanganese, and nickel, gold has no natural biological role. It is too<br \/>\nsoft for making tools; it is inconveniently heavy. And yet people<br \/>\nhave searched for it tirelessly, they have burrowed and blasted<br \/>\nthrough the earth and sifted through mountains of gravel to claim<br \/>\nan estimated 100,000 tonnes in the past five hundred years alone.<br \/>\n<strong>&#8216;Gold&#8217;, says Jacob Bronowski, &#8216;is the universal prize in all countries,<\/strong><br \/>\n<strong>in all cultures, in all ages.&#8217;<\/strong><\/p>\n<p>That doesn&#8217;t seem right to me. The <a href=\"http:\/\/en.wikipedia.org\/wiki\/Gold#Symbolism\">symbolism section on Wikipedia<\/a> seems to be pretty much only about indo-european cultures, and no data about, say, pre-contact African cultures. However, after my quick googling around, i didn&#8217;t find any more data about this.<\/p>\n<p>&#8211;<\/p>\n<p style=\"padding-left: 30px;\">The metals are the most familiar and recognizable of the chemical<br \/>\nelements to non-scientists &#8211; for everyone senses the uniqueness of<br \/>\nstolid iron, soft and ruddy copper, mercury&#8217;s liquid mirror. And<br \/>\namong these ponderous substances no element has more resonance<br \/>\nand rich associations than gold. It is an enduring symbol of<br \/>\neminence and purity. The best athletes win gold metals (in a trio of<br \/>\nmetals that echoes that of the oldest coinage); the best rock bands<br \/>\nwin golden discs. A band of gold seals the wedding vows, and fifty<br \/>\nyears later the metal valorizes the most exalted anniversary of<br \/>\nmarried bliss. Associations of gold sell everything from credit cards<br \/>\nto coffee. <strong>Platinum is rarer and more expensive, and some attempts<\/strong><br \/>\n<strong>have been made to give it even grander status than gold. But it will<\/strong><br \/>\n<strong>not work, because there are no legends or myths to support it.<\/strong> There<br \/>\ncan be no other element than gold whose chemical characteristics<br \/>\nhave been so responsible for lodging it firmly in our cultural<br \/>\ntraditions.<\/p>\n<p>Yes, they do. I have seen many such examples. The first three that came to mind are: 1) In Crash Bandicoot games, the player is rewarded with a platinum relic which is better than the gold relic (<a href=\"http:\/\/www.youtube.com\/watch?v=9rgnz3OEOcQ\">random video of this<\/a>), 2) In Starcraft 2, the <a href=\"http:\/\/starcraft.wikia.com\/wiki\/League_%28StarCraft_II%29#League_Types\">Platinum league is higher (better) than the Gold league<\/a>, 3) in <a href=\"http:\/\/en.wikipedia.org\/wiki\/Music_recording_sales_certification\">music sales classification<\/a>, platinum is better than gold. I&#8217;m sure that there are tons of more examples.<\/p>\n<p>&#8211;<\/p>\n<p style=\"padding-left: 30px;\">\u00a0So how many elements are there? I do not know, and neither does<br \/>\nanyone else. Oh, they can tell you how many natural elements there<br \/>\nare &#8211; how many we can expect to find at large in the universe. That<br \/>\nseries stops around uranium, element number 92.* But as to how<br \/>\nmany elements are possible &#8211; well, name a number. We have no idea<br \/>\nwhat the limit might be.<\/p>\n<p style=\"padding-left: 30px;\">* Elements slightly heavier than uranium, produced by radioactive decay (see<br \/>\nlater), are found in tiny amounts in natural uranium ores. Plutonium (element 94)<br \/>\nhas also been found in nature, a product of the element-forming processes that<br \/>\nhappen in dying stars. So it is a tricky matter to put a precise number on the<br \/>\nnatural elements.<\/p>\n<p>I thought that only atoms up to Uranium were natural, but apparently not. <a href=\"http:\/\/en.wikipedia.org\/wiki\/Chemical_element\">Wikipedia<\/a> lists 98 elements that are currently known to occur naturally, either on Earth or in some distant star. I had also conflated natural elements with elements that have at least one stable isotope. However, on reflection i see that i was just wrong, since <a href=\"http:\/\/en.wikipedia.org\/wiki\/Radon\">Radon<\/a> (Rn) occurs naturally but doesn&#8217;t have a stable isotope. There are a few other natural elements that also lack a stable isotope (as far as we know, anyway).<\/p>\n<p>&#8211;<\/p>\n<p style=\"padding-left: 30px;\">Polar ice contains tiny bubbles of trapped ancient air, within which<br \/>\nscientists can measure the amounts of minor (&#8216;trace&#8217;) gases such as<br \/>\ncarbon dioxide and methane. These are greenhouse gases, which<br \/>\nwarm the planet by absorbing heat radiated from the Earth&#8217;s<br \/>\nsurface. The ice cores show that levels of greenhouse gases in the<br \/>\natmosphere, controlled in the past by natural processes such as<br \/>\nplant growth on land and in the sea, have risen and fallen in near-<br \/>\nperfect synchrony with temperature changes. <strong>This provides strong<\/strong><br \/>\n<strong>evidence that the greenhouse effect regulates the Earth&#8217;s climate<\/strong>,<br \/>\nand helps us to anticipate the magnitude of the changes we might<br \/>\nexpect by adding further greenhouse gases to the atmosphere.<\/p>\n<p>No it doesn&#8217;t. The causal relation cud be some entirely other way. He might be right, but simply reasoning like that is a <a href=\"http:\/\/www.fallacyfiles.org\/noncause.html\">causal reasoning fallacy<\/a>. Also, for good fun, here are two funnies:<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone\" title=\"Correlation\" src=\"http:\/\/imgs.xkcd.com\/comics\/correlation.png\" alt=\"\" width=\"459\" height=\"185\" \/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone\" title=\"Correlation causation\" src=\"http:\/\/chaospet.com\/comics\/2009-12-28-corrr.png\" alt=\"\" width=\"700\" height=\"400\" \/><\/p>\n<p>&#8211;<\/p>\n<p style=\"padding-left: 30px;\">\u00a0An isotope of the rare element technetium, denoted <sup>99m<\/sup>Tc, is widely<br \/>\nused to form images of the heart, brain, lungs, spleen, and other<br \/>\norgans. Here the &#8216;m&#8217; indicates that the isotope, formed by decay of a<br \/>\nradioactive molybdenum isotope created by bombardment with<br \/>\nneutrons, is &#8216;metastable&#8217;, meaning only transiently stable. It decays<br \/>\nto &#8216;normal&#8217; &#8220;Tc by emitting two gamma rays, with a half-life of six<br \/>\nhours. This is a nuclear process that does not change either the<br \/>\natomic number or the atomic mass of the nucleus &#8211; it just sheds<br \/>\nsome excess energy.<\/p>\n<p style=\"padding-left: 30px;\">As a compound of <sup>99m<\/sup>Tc spreads through the body, the gamma<br \/>\nradiation produces an image of where the radioisotope has travelled.<br \/>\nBecause the two gamma rays are emitted simultaneously and in<br \/>\ndifferent directions, their paths can be traced back to locate the<br \/>\nemitting atom precisely at the point of crossing. This enables three-<br \/>\ndimensional images of organs to be constructed (Fig. 16). Scientists<br \/>\nare devising new technetium compounds that remain localized in<br \/>\nspecific organs. Eventually, the technetium is simply excreted in urine<\/p>\n<p>This is cool. Never heard of metastable isotopes before.<\/p>\n<p>&#8211;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>What this really means is that the classical elements are familiar representatives of the different physical states that matter can adopt. Earth represents not just soil or rock, but all solids. Water is the archetype of all liquids; air, of all gases and vapours. Fire is a strange one, for it is indeed a unique [&hellip;]<\/p>\n","protected":false},"author":17,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1107],"tags":[],"class_list":["post-2874","post","type-post","status-publish","format-standard","hentry","category-science","entry"],"_links":{"self":[{"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/posts\/2874","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/users\/17"}],"replies":[{"embeddable":true,"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/comments?post=2874"}],"version-history":[{"count":4,"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/posts\/2874\/revisions"}],"predecessor-version":[{"id":2882,"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/posts\/2874\/revisions\/2882"}],"wp:attachment":[{"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/media?parent=2874"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/categories?post=2874"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/emilkirkegaard.dk\/en\/wp-json\/wp\/v2\/tags?post=2874"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}